7/10
Mike Danenberg/Universal Studios Hollywood
The acappella group actually first started out as a trio with high school friends Kristie Maldonado, Mitch Grassi and Scott Hoying. But in 2011, Scott found out about auditions for The Sing-Off, and recruited the final two members, Avi Kaplan and Kevin Olusola, to complete the fivesome. They met for the first time the day before the audition, and their chemistry was so undeniable that their talents took them all the way to win the title.